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The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction

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dc.contributor.author Pottie, Ian
dc.contributor.author MacDonald, Frank
dc.contributor.author Carneiroa, Karina
dc.date.accessioned 2014-10-30T15:25:04Z
dc.date.available 2014-10-30T15:25:04Z
dc.date.issued 2011-02-08
dc.identifier.citation MacDonald, F. K., Carneiro, K. M. M., & Pottie, I. R. (2011). The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction. Tetrahedron Letters, 52(8), 891–893. doi:10.1016/j.tetlet.2010.12.056 en_US
dc.identifier.other 10.1016/j.tetlet.2010.12.056
dc.identifier.uri http://hdl.handle.net/10587/1419
dc.description.abstract Trimethylsilyl methylenenitronate reacts with both aliphatic and aromatic aldehydes in the presence of catalytic amounts of scandium(III) triflate to form the Henry reaction products in low (25%) to good yields (77%). This is the first example of this silyl nitronate undergoing a nitro-aldol reaction under an acid environment. en_US
dc.language.iso en en_US
dc.publisher Tetrahedron Letters en_US
dc.subject Mukaiyama nitro-aldol en_US
dc.subject 1,2-Nitroalcohol en_US
dc.subject Henry reaction en_US
dc.subject Silyl nitronate en_US
dc.subject Scandium triflate en_US
dc.type Article en_US
dc.title The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction en_US
dc.format.availability Full-text en_US


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